Phase change materials

[Piwoslaw]

This thread will be about phase change materials - parafin wax for higher temperature applications (solar, automotive), water/ice for lower temps, and anything else. I'll start with olive oil.

I found this page about using phase change thermal mass in the refrigerator to extend its off time. In this case it is olive oil, which has a freezing temperature only a few degrees higher than water, allowing it store more thermal energy at refrigerator temps than water.

OK, this got me excited, so I read up on freezing olive oil. According to this, olive oil doesn't really freeze because it doesn't have a regular crystal structure. Instead it just becomes more and more viscous. This page explains it even further. So, if olive oil doesn't technically "freeze", but only "slows down", then does it really change phase and store more energy than just changing temperature?

On the other hand, the author of the this page cites some numbers for olive oil's heat of fusion, so maybe it is a phase change? Here's a quote:

Water has a heat of fusion of about 100, this means it takes 100 times as much energy to freeze 32 degree water as it does to raise water 1 degree from 32.
The problem with using water for a fridge is you will freeze your food if you try to use the heat of fusion of water to keep cool.
Olive oil has a heat of fusion of 48 but it starts to freeze at 40 degrees Fahrenheit, it also has one half the heat capacity of water , this means it takes 4 gallons of olive oil to hold as much heat as 1 gallon of water( at fusion temp), but it thaws at 32-40 degrees which means it will hold the refrigerator at 32-40 degrees for a very long time.

So I'm a little lost: If I have about 11 liters of water bottled up in my fridge, then will replacing it with a similar amount of olive oil extend its "coastdown time"?