On my side of the pond, one of the possiblities for roofing is styrofoam mated with tar shingles:
Styrofoam has an R-value of 3.2-4 (molded) or 3.6-5 (extruded).
I've seen metal roofs insulated with styrofoam or mineral wool.
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Ecorenovation - the bottomless piggy bank that tries to tame the energy hog.
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